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CHEM 123 ChIRP
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  • Part 1: THERMODYNAMICS
    • Section 0: Acids and Bases
      • 0.1 Strong and weak acids and bases
      • 0.2 pH of a strong acid/base solution
      • 0.3 pH of a weak acid/base solution
      • 0.4 pH of a salt solution
      • 0.5 Mixtures of acids and bases
      • 0.6 Buffers
    • Section 1: Introduction to Thermodynamics
      • 1.1: Systems and states
      • 1.2: State variables
      • 1.3: Process variables
      • 1.4: First Law of Thermodynamics
      • 1.5: Constant volume calorimetry
    • Section 2: Enthalpy
      • 2.1: Constant pressure calorimetry
      • 2.2: Standard states
      • 2.3: Formation reactions
      • 2.4: Hess’ law
    • Section 3: Entropy
      • 3.1: Introduction to statistical mechanics
      • 3.2: Thermodynamics interpretation of entropy
      • 3.3: Second Law of Thermodynamics
      • 3.4: Third Law of Thermodynamics
    • Section 4: Gibbs Free Energy
      • 4.1: Defining Gibbs free energy
      • 4.2: Standard Gibbs free energy
      • 4.3: van’t Hoff plots
  • Part 2: KINETICS
    • Section 1: Introduction to Kinetics
      • 1.1: Thermodynamics vs Kinetics
      • 1.2: Reaction rate
      • 1.3: Law of mass action
      • 1.4: First order integrated rate law
      • 1.5: Second order integrated rate law
      • 1.6 Zeroth order integrated rate law
      • 1.7: Half-life
    • Section 2: Activation Energy
      • 2.1: Arrhenius equation
      • 2.2: Eyring equation
    • Section 3: Multi-step Reactions
      • 3.1: Multi-step reactions with slow first step
      • 3.2: Multi-step reactions with slow second step
      • 3.3: Steady state approximation
      • 3.4: Predicting reaction mechanisms
  • Part 3: STRUCTURE + BONDING
    • Section 1: Representing Organic Structures
      • 1.1: Condensed structures
      • 1.2: Lewis dot stuctures
      • 1.3: Kekule structures
      • 1.4: Line bond structures
      • 1.5: Wedge-dash structures
      • 1.6: Constitutional isomers
    • Section 2: Organic Nomenclature
      • 2.1: Alkane nomenclature
      • 2.2: Alkene and alkyne nomenclature
      • 2.3: Common names for branching substituents
      • 2.4: Cyclic hydrocarbon nomenclature
      • 2.5: Identifying functional groups
      • 2.6: Naming low-priority functional groups (ethers, sulfides, and halides)
      • 2.7: High priority functional groups
      • 2.8: Common names
    • Section 3: Bonding Theories
      • 3.1: Valence Shell Electron Pair Repulsion (VSEPR) Theory
      • 3.2: Valence Bond Theory
      • 3.3: Molecular Orbital (MO) Theory
      • 3.4: Frontier Molecular Orbital Theory
    • Section 4: Electronic distribution in molecules
      • 4.1: Electronegativity
      • 4.2: Induction
      • 4.3: Atom size (Polarizability)
      • 4.4: Resonance
    • Section 5: Qualitative Acidity Predictions
      • 5.1: Acid-base equilibria
      • 5.2: Relative strengths of charged acids and bases
      • 5.3: Relative strengths of neutral acids and bases
    • Section 6: Acyclic Conformational Isomers
      • 6.1: Molecular rotation in acyclic saturated conformational isomers
      • 6.2: Representing conformations
      • 6.3: Sawhorse projections
      • 6.4: Newman Projections
      • 6.5: Conformational energies
    • Section 7: Cyclic saturated hydrocarbons
      • 7.1: Drawing 6-membered rings
      • 7.2: Newman Projections of 6-membered rings
      • 7.3: Chair flips
      • 7.4: Monosubstituted cyclohexanes
      • 7.5: Disubstituted cyclohexanes
  • Part 4: STEREOCHEMISTRY
    • Section 1: Alkenes
      • 1.1 Bonding and Structure
      • 1.2 Cis/Trans Nomenclature
      • 1.3: Alkene Nomenclature Part 1 – CIP Rules
      • 1.4 Alkene Nomenclature Part 2: E/Z
    • Section 2: Enantiomers and Diastereomers
      • 2.1: Chirality and enantiomers
      • 2.2: Asymmetric centres and stereocentres
      • 2.3: R/S nomenclature
      • 2.4: Diastereomers
      • 2.5: Meso compounds
      • 2.6: Fischer projections
      • 2.7: Differentiating Stereoisomers
      • 2.8 Properties of chiral species I
      • 2.9 Properties of chiral species II
  • Part 5: REACTIVITY
    • Section 1: SN2 Reactions
      • 1.1: Conventions and definitions
      • 1.2: Mechanism and kinetics
      • 1.3: Electrophile, nucleophile, and leaving group
      • 1.4: Stereochemistry
    • Section 2: SN1 Reactions
      • 2.1: Mechanism and Kinetics
      • 2.2: Electrophile, nucleophile, and leaving group
      • 2.3: Acid-Catalyzed Mechanism
      • 2.4: Differentiating SN2 from SN1 Reactions
    + Key Points
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    Last updated on July 1, 2025 @1:25 am

    Home
    Part 1: THERMODYNAMICS
    Section 0: Acids and Bases
    0.1 Strong and weak acids and bases
    0.2 pH of a strong acid/base solution
    0.3 pH of a weak acid/base solution
    0.4 pH of a salt solution
    0.5 Mixtures of acids and bases
    0.6 Buffers
    Section 1: Introduction to Thermodynamics
    1.1: Systems and states
    1.2: State variables
    1.3: Process variables
    1.4: First Law of Thermodynamics
    1.5: Constant volume calorimetry
    Section 2: Enthalpy
    2.1: Constant pressure calorimetry
    2.2: Standard states
    2.3: Formation reactions
    2.4: Hess’ law
    Section 3: Entropy
    3.1: Introduction to statistical mechanics
    3.2: Thermodynamics interpretation of entropy
    3.3: Second Law of Thermodynamics
    3.4: Third Law of Thermodynamics
    Section 4: Gibbs Free Energy
    4.1: Defining Gibbs free energy
    4.2: Standard Gibbs free energy
    4.3: van't Hoff plots
    Part 2: KINETICS
    Section 1: Introduction to Kinetics
    1.1: Thermodynamics vs Kinetics
    1.2: Reaction rate
    1.3: Law of mass action
    1.4: First order integrated rate law
    1.5: Second order integrated rate law
    1.6 Zeroth order integrated rate law
    1.7: Half-life
    Section 2: Activation Energy
    2.1: Arrhenius equation
    2.2: Eyring equation
    Section 3: Multi-step Reactions
    3.1: Multi-step reactions with slow first step
    3.2: Multi-step reactions with slow second step
    3.3: Steady state approximation
    3.4: Predicting reaction mechanisms
    Part 3: STRUCTURE + BONDING
    Section 1: Representing Organic Structures
    1.1: Condensed structures
    1.2: Lewis dot stuctures
    1.3: Kekule structures
    1.4: Line bond structures
    1.5: Wedge-dash structures
    1.6: Constitutional isomers
    Section 2: Organic Nomenclature
    2.1: Alkane nomenclature
    2.2: Alkene and alkyne nomenclature
    2.3: Common names for branching substituents
    2.4: Cyclic hydrocarbon nomenclature
    2.5: Identifying functional groups
    2.6: Naming low-priority functional groups (ethers, sulfides, and halides)
    2.7: High priority functional groups
    2.8: Common names
    Section 3: Bonding Theories
    3.1: Valence Shell Electron Pair Repulsion (VSEPR) Theory
    3.2: Valence Bond Theory
    3.3: Molecular Orbital (MO) Theory
    3.4: Frontier Molecular Orbital Theory
    Section 4: Electronic distribution in molecules
    4.1: Electronegativity
    4.2: Induction
    4.3: Atom size (Polarizability)
    4.4: Resonance
    Section 5: Qualitative Acidity Predictions
    5.1: Acid-base equilibria
    5.2: Relative strengths of charged acids and bases
    5.3: Relative strengths of neutral acids and bases
    Section 6: Acyclic Conformational Isomers
    6.1: Molecular rotation in acyclic saturated conformational isomers
    6.2: Representing conformations
    6.3: Sawhorse projections
    6.4: Newman Projections
    6.5: Conformational energies
    Section 7: Cyclic saturated hydrocarbons
    7.1: Drawing 6-membered rings
    7.2: Newman Projections of 6-membered rings
    7.3: Chair flips
    7.4: Monosubstituted cyclohexanes
    7.5: Disubstituted cyclohexanes
    Part 4: STEREOCHEMISTRY
    Section 1: Alkenes
    1.1 Bonding and Structure
    1.2 Cis/Trans Nomenclature
    1.3: Alkene Nomenclature Part 1 – CIP Rules
    1.4 Alkene Nomenclature Part 2: E/Z
    Section 2: Enantiomers and Diastereomers
    2.1: Chirality and enantiomers
    2.2: Asymmetric centres and stereocentres
    2.3: R/S nomenclature
    2.4: Diastereomers
    2.5: Meso compounds
    2.6: Fischer projections
    2.7: Differentiating Stereoisomers
    2.8 Properties of chiral species I
    2.9 Properties of chiral species II
    Part 5: REACTIVITY
    Section 1: SN2 Reactions
    1.1: Conventions and definitions
    1.2: Mechanism and kinetics
    1.3: Electrophile, nucleophile, and leaving group
    1.4: Stereochemistry
    Section 2: SN1 Reactions
    2.1: Mechanism and Kinetics
    2.2: Electrophile, nucleophile, and leaving group
    2.3: Acid-Catalyzed Mechanism
    2.4: Differentiating SN2 from SN1 Reactions
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    Vancouver, BC Canada V6T 1Z1
    Website chirp1.chem.ubc.ca
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