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CHEM 123 ChIRP

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Part 1: THERMODYNAMICS
Part 2: KINETICS
Part 3: STRUCTURE + BONDING
Part 4: STEREOCHEMISTRY
- Section 1: Alkenes
- Section 2: Enantiomers and Diastereomers
Part 5: REACTIVITY
- Section 1: SN2 Reactions
- Section 2: SN1 Reactions

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Part 1: THERMODYNAMICS

Section 0: Acids and Bases

0.1 Strong and weak acids and bases

0.2 pH of a strong acid/base solution

0.3 pH of a weak acid/base solution

0.4 pH of a salt solution

0.5 Mixtures of acids and bases

0.6 Buffers

Section 1: Introduction to Thermodynamics

1.1: Systems and states

1.2: State variables

1.3: Process variables

1.4: First Law of Thermodynamics

1.5: Constant volume calorimetry

Section 2: Enthalpy

2.1: Constant pressure calorimetry

2.2: Standard states

2.3: Formation reactions

2.4: Hess’ law

Section 3: Entropy

3.1: Introduction to statistical mechanics

3.2: Thermodynamics interpretation of entropy

3.3: Second Law of Thermodynamics

3.4: Third Law of Thermodynamics

Section 4: Gibbs Free Energy

4.1: Defining Gibbs free energy

4.2: Standard Gibbs free energy

4.3: van't Hoff plots

Part 2: KINETICS

Section 1: Introduction to Kinetics

1.1: Thermodynamics vs Kinetics

1.2: Reaction rate

1.3: Law of mass action

1.4: First order integrated rate law

1.5: Second order integrated rate law

1.6 Zeroth order integrated rate law

1.7: Half-life

Section 2: Activation Energy

2.1: Arrhenius equation

2.2: Eyring equation

Section 3: Multi-step Reactions

3.1: Multi-step reactions with slow first step

3.2: Multi-step reactions with slow second step

3.3: Steady state approximation

3.4: Predicting reaction mechanisms

Part 3: STRUCTURE + BONDING

Section 1: Representing Organic Structures

1.1: Condensed structures

1.2: Lewis dot stuctures

1.3: Kekule structures

1.4: Line bond structures

1.5: Wedge-dash structures

1.6: Constitutional isomers

Section 2: Organic Nomenclature

2.1: Alkane nomenclature

2.2: Alkene and alkyne nomenclature

2.3: Common names for branching substituents

2.4: Cyclic hydrocarbon nomenclature

2.5: Identifying functional groups

2.6: Naming low-priority functional groups (ethers, sulfides, and halides)

2.7: High priority functional groups

2.8: Common names

Section 3: Bonding Theories

3.1: Valence Shell Electron Pair Repulsion (VSEPR) Theory

3.2: Valence Bond Theory

3.3: Molecular Orbital (MO) Theory

3.4: Frontier Molecular Orbital Theory

Section 4: Electronic distribution in molecules

4.1: Electronegativity

4.2: Induction

4.3: Atom size (Polarizability)

4.4: Resonance

Section 5: Qualitative Acidity Predictions

5.1: Acid-base equilibria

5.2: Relative strengths of charged acids and bases

5.3: Relative strengths of neutral acids and bases

Section 6: Acyclic Conformational Isomers

6.1: Molecular rotation in acyclic saturated conformational isomers

6.2: Representing conformations

6.3: Sawhorse projections

6.4: Newman Projections

6.5: Conformational energies

Section 7: Cyclic saturated hydrocarbons

7.1: Drawing 6-membered rings

7.2: Newman Projections of 6-membered rings

7.3: Chair flips

7.4: Monosubstituted cyclohexanes

7.5: Disubstituted cyclohexanes

Part 4: STEREOCHEMISTRY

Section 1: Alkenes

1.1 Bonding and Structure

1.2 Cis/Trans Nomenclature

1.3: Alkene Nomenclature Part 1 – CIP Rules

1.4 Alkene Nomenclature Part 2: E/Z

Section 2: Enantiomers and Diastereomers

2.1: Chirality and enantiomers

2.2: Asymmetric centres and stereocentres

2.3: R/S nomenclature

2.4: Diastereomers

2.5: Meso compounds

2.6: Fischer projections

2.7: Differentiating Stereoisomers

2.8 Properties of chiral species I

2.9 Properties of chiral species II

Part 5: REACTIVITY

Section 1: SN2 Reactions

1.1: Conventions and definitions

1.2: Mechanism and kinetics

1.3: Electrophile, nucleophile, and leaving group

1.4: Stereochemistry

Section 2: SN1 Reactions

2.1: Mechanism and Kinetics

2.2: Electrophile, nucleophile, and leaving group

2.3: Acid-Catalyzed Mechanism

2.4: Differentiating SN2 from SN1 Reactions

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Last updated on December 19, 2016 @5:54 pm

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